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Structure, function and diversity of the healthy human microbiome

The accumulated iron subsequently contributes to lipid peroxidation through two principal mechanisms: by participating in the Fenton reaction to generate ROS, and by serving as an essential cofactor for lipoxygenases (LOXs), thereby directly catalyzing membrane lipid peroxidation

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Furthermore, these internal benefits are reflected externally in clearer skin, reduced breakouts, and a more vibrant complexion

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While free NAPQI is the direct cause of toxicity, it cannot be detected or quantified in its free form in plasma or assay buffers due to its immediate reactivity with thiols and proteins