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An extra lysine residue is added beyond the endogenous sequence, bearing a chemical modification referred to as N-3-maleimidopropionic acid (MPA)
It's already used in emergency medicine to help patients in a toxic crisis, such as ingestion of poisonous levels of heavy metals
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2005 Sep;26(3):449-52
If the Nobel committee had recognized the tripeptide's significance earlier, research funding would have shifted toward intracellular antioxidants in the 1940s rather than the 1970s, potentially identifying the glutathione-peroxidase system 20 years sooner
B 12r and B 12s can be prepared from cyanocobalamin by controlled potential reduction, or chemical reduction using sodium borohydride in alkaline solution, zinc in acetic acid, or by the action of thiols
